聚合物纳米微球封堵剂CQ-NSA性能研究

钻采工艺 ›› 2022, Vol. 45 ›› Issue (2): 115-119.

聚合物纳米微球封堵剂CQ-NSA性能研究

陶怀志^1,2，陈俊斌^1,2，王兰^1,2，吴谦³

1 油气田应用化学四川省重点实验室 2 中国石油川庆钻探工程有限公司钻采工程技术研究院 3 中国石油川庆钻探工程有限公司安全环保质量监督检测研究院

出版日期:2022-03-25 发布日期:2022-04-28
作者简介:陶怀志（1983-）博士，高级工程师，主要从事钻井液技术研发。
基金资助:
中国石油集团重大工程技术现场实验项目“页岩气长水平段井水基钻井液现场实验”（编号：2018F-21）。

Study on Property of Polymer Nanoparticle Blocking Agent CQ-NSA

TAO Huaizhi^1,2，CHEN Junbin^1,2，WANG Lan^1,2，WU Qian³

1. Oil & Gas Field Applied Chemistry Key Laboratory of Sichuan Province, Chengdu, Sichuan 610500, China; 2. CCDC Drilling & Production Engineering Technology Research Institute, Guanghan, Sichuan 618300, China; 3. CNPC Safety and Environment Quality Supervision and Testing Institute Guanghan, Sichuan 618300, China

Online:2022-03-25 Published:2022-04-28

摘要/Abstract

摘要：

针对页岩储层纳米级孔缝封堵的问题，研究了水基钻井液聚合物纳米微球封堵剂CQ-NSA的分散性、封堵性与配伍性。通过超声分散，其粒度中径为82.14 ；采用常规高速搅拌，17.5%的颗粒仍保持纳米级分布。将CQ-NSA加入膨润土浆中，总颗粒中仍有 6%的颗粒呈纳米级分布。CQ-NSA加量在1.0之间可以显著降低滤饼渗透率!有效降低膨润土浆与体系配方的高温高压渗透封堵仪滤失量,表明CQ-NSA具有良好的封堵性能。流变性能分析结果表明，CQ-NSA加量不超1.5%，对膨润土浆与水基钻井液体系的流变性能影响不大，具有较好的配伍性能。该研究为页岩气水基钻井液用纳米封堵剂提供了理论与实验依据。

关键词:

聚合物, 纳米封堵剂, 分散性, 配伍性, 封堵性

Abstract:

Aiming at the problem of nanometer aperture sealing in shale reservoir, the property of dispersion, blocking and compatibility of polymer nanoparticle blocking agent CQ-NSA were studied. The particle diameter was 82. 14 nm by ultra sonic dispersion. Using conventional high-speed agitation,17.5% of the particles remained nanoscale distribution. When CQ-NSA was added into bentonite slurry, there were still 6% of the total particles in the nanoscale distribution. The dosage of CQ-NSA as blocking agent between 1.0% and 1.5% can significantly reduce the permeability of mud cake, effectively reduce the filtration loss measured by the PPA blocking tester of hentonite slurry and drilling fluid system, indicating that CQ-NSA has good blocking performance.The results of rheological analysis show that the dosage of CQ-NSA does not exceed 1.5% , which has little effect on the rheological properties of bentonite slurry and drilling fluid system, and has good compatibility. This study provided a theoretical and experimental basis for nanoparitical blocking agent used in water-based drilling fluid.

Key words:

polymer, nanoparticle blocking agent, dispersion, compatibility, blocking performance

陶怀志, 陈俊斌, 王兰, 吴谦. 聚合物纳米微球封堵剂CQ-NSA性能研究[J]. 钻采工艺, 2022, 45(2): 115-119.

TAO Huaizhi, CHEN Junbin, WANG Lan, WU Qian. Study on Property of Polymer Nanoparticle Blocking Agent CQ-NSA [J]. Drilling & Production Technology, 2022, 45(2): 115-119.

参考文献

[1] 王治法，刘贵传，刘金华，等. 国外高性能水基钻井液研究的最新进展[J].钻井液与完井液，2009，26（5）：69-72.
WANG Zhifa, LIU Guichuan, LIU Jinhua, et al. Oversea New Progresses in High Performance Water Base Drilling Fluid Research[J]. Drilling Fluid and Completion Fluid, 2009, 26(5):60-68.
[2] 陈士奎，谭枭麟，王荐，等.页岩气高性能水基钻井液技术研究[J].石油化工应用，2018，12（37）：57-60.
CHEN Shikui, TAN Xiaolin, WANG Jian, et al. Research of Shale Gas High Performance Water Base Drilling Fluid Technique[J]. Petrochemical Industry Application, 2018, 12(37):57-60.
[3] 孙思维，刘学松，范聪，等. 页岩气水基钻井液技术分析[J]. 当代化工研究，2017，11：25-26.
SUN Siwei, LIU Xuesong, FAN Cong, et al. Shale Gas Water Based Drilling Fluid Technology Analysis[J]. Chemical Intermediate, 2017, 11:25-26.
[4] 赵虎，司西强，王爱芳. 国内页岩气水基钻井液研究与应用进展[J]. 天然气勘探与开发，2018，3（41）：90-95.
ZHAO Hu, SI Xiqiang, WANG Aifang. Water-Based Drilling Fluid and its Application to China Shale Gas Reservoirs[J]. Natural Gas Exploration and Development, 2018, 3(41):90-95.
[5] ZAKARIA M F.HUSEIN M. HARELAND G. Novel nanoparticle-based drilling fluid with improved characteristics[C]//SPE International Oilfield Nanotechnology Conference and Exhibition,June 12-142012Noordwijk，The Netherlands. Richardson,Texas, USA: OnePetro，2012.
[6] 黄进军，刘伟，李春霞. 纳米封堵剂NF-1的制备与性能评价[J]. 钻井液与完井液，2016, 5（33）：15-19.
Huang Jinjun, Liu Wei, Li Chunxia. Development and Evaluation of the Nano Plugging Agent NF-1[J]. Drilling Fluid and Completion Fluid, 2016, 5(33):15-19.
HOELSCHER K P, DE STEFANO G. RILEY M, et al. Application of nanotechnology in drilling fluids [C]//SPE International Oilfield Nanotechnology Conference and Exhibition, June 12-14, 2012 Noordwijk,The Netherlands. Richardson，Texas，USA:OnePetro，2012
[8] 付艳，黄进军，武元鹏，等. 钻井液用纳米粒子封堵行能的评价[J]. 重庆科技学院学报（自然科学版），2013,6（15）：30-31.
FU Yan, HUANG Jinjun, WU Yuanpeng, et al. Evaluation of Nanometer Particle Plugging Material for Drilling Fluid[J]. Journal of Chongqing University of Science and Technology (Natural Science Edition), 2013, 6(15):30-31
[9] 徐传奇，李海燕，张小峰，等. 纳米封堵剂性能评价及机理分析[J]. 钻采工艺，2019，3（42）：100-103.
XU Chuanqi, LO Haiyan, ZHANG Xiaofeng, et al. Performance Evaluation for New Type Nano Plugging Agents and its Mechanism Analysis[J]. Drilling and Production Technology, 2019, 3(42):100-103.

[1]	王建平, 贾红娟, 佘小兵, 范春林, 张磊, 秦国伟. 微米级石墨粉增强堵水凝胶性能实验研究[J]. 钻采工艺, 2022, 45(5): 123-127.
[2]	曹世平, 吴申尧, 曾家新, 景岷嘉, 张亚萍. BK910油基钻井液用堵漏剂的评价及应用[J]. 钻采工艺, 2020, 43(6): 97-99.
[3]	邓仕奎, 李华坤, 陈鑫, 向朝纲, 高利华, 王棋. 土库曼斯坦白垩系不稳定地层钻井液技术[J]. 钻采工艺, 2020, 43(5): 91-94.
[4]	徐传奇, 李海燕, 张小锋, 李德权, 张睿荫, 崔浪, 李昱. 纳米封堵剂性能评价及机理分析[J]. 钻采工艺, 2019, 42(2): 100-103.
[5]	刘卫东, 朱晓虎, 蒋文海, 樊萍, 王悦和, 都炳锋. 页岩微裂缝模拟实验评价[J]. 钻采工艺, 2019, 42(2): 104-107.
[6]	刘　伟, 柳　娜, 吴满祥, 涂海海, 曹　辉, 陈在君. 抗温型低渗透钻井液在富顺页岩气坛２０３井的应用[J]. 钻采工艺, 2015, 38(6): 87-.
[7]	邵平, 张伟, 周华安, 徐新钮, 孙俊, 谢建安, 崔晓明. 准噶尔南缘重点超深探井DF1井钻井液技术[J]. 钻采工艺, 2014, 37(4): 87-90.
[8]	黎金明，蔺文洁，崔贵涛，赵海峰，王伟良，付微风. 苏里格气田分支井钻（完）井液技术[J]. 钻采工艺, 2014, 37(1): 18-20.
[9]	庞炳章，管　申，方满宗，陈晓东. 崖城１３－１－Ａ１２Ｓａｈ高温超低压大位移井钻井液技术及应用[J]. 钻采工艺, 2013, 36(2): 97-100.
[10]	谢晓永, 唐洪明, 孟英峰, 王春华. 川西洛带气田致密砂岩污水回注实验室研究[J]. 钻采工艺, 2007, 30(5): 39-41.
[11]	刘永兵,杨燕, 蒲万芬. 驱油用NACP泡沫体系的配方研究及效果评价[J]. 钻采工艺, 2007, 30(2): 120-123.